全文获取类型
收费全文 | 617篇 |
免费 | 23篇 |
国内免费 | 1篇 |
专业分类
化学 | 366篇 |
晶体学 | 3篇 |
力学 | 34篇 |
数学 | 136篇 |
物理学 | 102篇 |
出版年
2023年 | 7篇 |
2022年 | 11篇 |
2021年 | 35篇 |
2020年 | 14篇 |
2019年 | 19篇 |
2018年 | 29篇 |
2017年 | 25篇 |
2016年 | 27篇 |
2015年 | 19篇 |
2014年 | 33篇 |
2013年 | 63篇 |
2012年 | 45篇 |
2011年 | 56篇 |
2010年 | 28篇 |
2009年 | 31篇 |
2008年 | 43篇 |
2007年 | 25篇 |
2006年 | 25篇 |
2005年 | 15篇 |
2004年 | 21篇 |
2003年 | 11篇 |
2002年 | 6篇 |
2001年 | 9篇 |
2000年 | 10篇 |
1999年 | 6篇 |
1998年 | 6篇 |
1997年 | 5篇 |
1994年 | 1篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1987年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1973年 | 1篇 |
1940年 | 2篇 |
排序方式: 共有641条查询结果,搜索用时 312 毫秒
101.
The geometry, frequency and intensity of the vibrational bands of 8-hydroxyquinoline and its 5,7-dichloro, 5,7-dibromo, 5,7-diiodo
and 5,7-dinitro derivatives were obtained by the density functional theory (DFT) calculations with Becke3-Lee-Parr (B3LYP)
functional and 6-31G* basis set. The effects of chloride, bromide, iodide and nitro substituent on the vibrational frequencies
of 8-hydroxyquinoline have been investigated. The assignments have been proposed with aid of the results of normal coordinate
analysis. The observed and calculated spectra are found to be in good agreement.
相似文献
102.
An electrochemical biosensor with a new bioorganometallic approach for the detection of human immunodeficiency virus (HIV) type 1 protease (HIV-1 PR) using surface-bound ferrocenoyl (Fc)-pepstatin conjugates is presented. 相似文献
103.
Khaled SM Sui R Charpentier PA Rizkalla AS 《Langmuir : the ACS journal of surfaces and colloids》2007,23(7):3988-3995
Inorganic-polymer nanocomposites are of significant interest for emerging materials due to their improved properties and unique combination of properties. Methacrylic acid (MA), a functionalization agent that can chemically link TiO2 nanomaterials (n-TiO2) and polymer matrix, was used to modify the surface of n-TiO2 using a Ti-carboxylic coordination bond. Then, the double bond in MA was copolymerized with methyl methacrylate (MMA) to form a n-TiO2-PMMA nanocomposite. The resulting n-TiO2-PMMA nanocomposite materials were characterized by using thermal analysis, electron microscopy, and elemental analysis. The dynamic mechanical properties (Young's and shear modulus) were measured using an ultrasonic pulse technique. The electron microscopy results showed a good distribution of the nanofillers in the polymer matrix. The glass transition temperature, thermal degradation temperature, and dynamic elastic moduli of the nanocomposites were shown to increase with an increase in the weight percentage of nanofibers in the composite. The resulting nanocomposites exhibited improved elastic properties and have potential application in dental composites and bone cements. 相似文献
104.
Sheikhahmadi Haidar Mohammadi Abolhassan Aghamohammadi Ali Harko Tiberiu Herrera Ramón Corda Christian Abebe Amare Saaidi Khaled 《The European Physical Journal C - Particles and Fields》2019,79(12):1-10
The European Physical Journal C - We study the Yukawa model with one scalar and one axial scalar fields, coupled to N copies of Dirac fermions, in curved spacetime background. The theory possesses... 相似文献
105.
106.
Nadia?Benhalima Khaled?Toubal Abdelkader?ChouaihEmail author Giuseppe?Chita Sabino?Maggi Ayada?Djafri Fodil?Hamzaoui 《Journal of chemical crystallography》2011,41(11):1729-1736
Abstract
We report here the synthesis of (Z)-5-(4-nitrobenzyliden)-3-N(2-ethoxyphenyl)-2-thioxo-thiazolidin-4-one (ARNO) compound. The crystal structure has been determined by X-ray diffraction. The compound crystallizes in the triclinic system with space group P[`1] P\bar{1} and cell parameters: a = 9.1289(19), b = 9.3717(7), c = 12.136(3) ?, α = 102.133(11)°, β = 90.99(2)°, γ = 117.165(9)°, V = 895.4(3) ?3 and Z = 2. The structure has been refined to a final R = 0.05 for 2591 observed reflections. The refined structure was found to be significantly non planar. The molecule exhibits intermolecular hydrogen bond of type C–H⋯O and C–H⋯S. ab initio calculations were also were performed at Hartree–Fock and density functional theory levels. The full HF and DFT geometry optimization was carried out using LANL2DZ, 6-31G* and B3LYP/6-31+G** basis sets. The optimized geometry of the title compound was found to be consistent structure determined by X-ray diffraction. The minimum energy of geometrical structure is obtained by using level HF/LANL2DZ basis sets. 相似文献107.
This paper proposes a new approach for decision making under uncertainty based on influence diagrams and possibility theory. The so-called qualitative possibilistic influence diagrams extend standard influence diagrams in order to avoid difficulties attached to the specification of both probability distributions relative to chance nodes and utilities relative to value nodes. In fact, generally, it is easier for experts to quantify dependencies between chance nodes qualitatively via possibility distributions and to provide a preferential relation between different consequences. In such a case, the possibility theory offers a suitable modeling framework. Different combinations of the quantification between chance and utility nodes offer several kinds of possibilistic influence diagrams. This paper focuses on qualitative ones and proposes an indirect evaluation method based on their transformation into possibilistic networks. The proposed approach is implemented via a possibilistic influence diagram toolbox (PIDT). 相似文献
108.
109.
Ultraviolet-B radiation effects on the structure and function of lower trophic levels of the marine planktonic food web 总被引:2,自引:0,他引:2
Ferreyra GA Mostajir B Schloss IR Chatila K Ferrario ME Sargian P Roy S Prod'homme J Demers S 《Photochemistry and photobiology》2006,82(4):887-897
The impact of UV-B radiation (UVBR; 280-320 nm) on lower levels of a natural plankton assemblage (bacteria, phytoplankton and microzooplankton) from the St. Lawrence Estuary was studied during 9 days using several immersed outdoor mesocosms. Two exposure treatments were used in triplicate mesocosms: natural UVBR (N treatment, considered as the control treatment) and lamp-enhanced UVBR (H treatment, simulating 60% depletion of the ozone layer). A phytoplankton bloom developed after day 3, but no significant differences were found between treatments during the entire experiment for phytoplankton biomass (chlorophyll a and cell carbon) nor for phytoplankton cell abundances from flow cytometry and optical microscopy of three phytoplankton size classes (picoplankton, nanoplankton and microplankton). In contrast, bacterial abundances showed significantly higher values in the H treatment, attributed to a decrease in predation pressure due to a dramatic reduction in ciliate biomass (approximately 70-80%) in the H treatment relative to the N treatment. The most abundant ciliate species were Strombidinium sp., Prorodon ovum and Tintinnopsis sp.; all showed significantly lower abundances under the H treatment. P. ovum was the less-affected species (50% reduction in the H treatment compared with that of the N control), contrasting with approximately 90% for the other ones. Total specific phytoplanktonic and bacterial production were not affected by enhanced UVBR. However, both the ratio of primary to bacterial biomass and production decreased markedly under the H treatment. In contrast, the ratio of phytoplankton to bacterial plus ciliate carbon biomass showed an opposite trend than the previous results, with higher values in the H treatment at the end of the experiment. These results are explained by the changes in the ciliate biomass and suggest that UVBR can alter the structure of the lower levels of the planktonic community by selectively affecting key species. On the other hand, linearity between particulate organic carbon (POC) and estimated planktonic carbon was lost during the postbloom period in both treatments. On the basis of previous studies, our results can be attributed to the aggregation of carbon released by cells to the water column in the form of transparent exopolymer particles (TEPs) under nutrient limiting conditions. Unexpectedly, POC during such a period was higher in the H treatment than in controls. We hypothesize a decrease in the ingestion of TEPs by ciliates, in coincidence with increased DOC release by phytoplankton cells under enhanced UVBR. The consequences of such results for the carbon cycle in the ocean are discussed. 相似文献
110.
Fitzgerald JE Robinson RL Gasem KA 《Langmuir : the ACS journal of surfaces and colloids》2006,22(23):9610-9618
The simplified local-density (SLD) theory was investigated regarding its ability to provide accurate representations and predictions of high-pressure supercritical adsorption isotherms encountered in coalbed methane (CBM) recovery and CO2 sequestration. Attention was focused on the ability of the SLD theory to predict mixed-gas adsorption solely on the basis of information from pure gas isotherms using a modified Peng-Robinson (PR) equation of state (EOS). An extensive set of high-pressure adsorption measurements was used in this evaluation. These measurements included pure and binary mixture adsorption measurements for several gas compositions up to 14 MPa for Calgon F-400 activated carbon and three water-moistened coals. Also included were ternary measurements for the activated carbon and one coal. For the adsorption of methane, nitrogen, and CO2 on dry activated carbon, the SLD-PR can predict the component mixture adsorption within about 2.2 times the experimental uncertainty on average solely on the basis of pure-component adsorption isotherms. For the adsorption of methane, nitrogen, and CO2 on two of the three wet coals, the SLD-PR model can predict the component adsorption within the experimental uncertainties on average for all feed fractions (nominally molar compositions of 20/80, 40/60, 60/40, and 80/20) of the three binary gas mixture combinations, although predictions for some specific feed fractions are outside of their experimental uncertainties. 相似文献